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New Guide Fills Information Gaps on Hydrogen Safety
Karen Hall, National Hydrogen Association


As you might imagine, industry professionals, emergency responders and even potential consumers have many questions about hydrogen, particularly about how to handle it safely.

A new book, NFPA's Guide to Gas Safety, addresses the safety and handling of many compressed gases, including hydrogen. The 553-page guide is a compilation of chapters written by subject matter experts and includes two that specifically address hydrogen safety issues- hydrogen dispensing operations and hydrogen dispersion. Other chapters address issues common among many different gases. The following is a short summary of the sections that pertain most to hydrogen safety:

Chapters 1-4 cover handling, emergency response, process safety, and risk management plans for compressed gases in general.

Chapter 9 covers industrial gases.

Chapter 13 addresses storage and refuelling of compressed natural gas and hydrogen. Table 13.2 provides key physical properties of hydrogen compared to other fuels and Figure 13.10 provides a diagram of a typical hydrogen fuelling station.

Chapter 14 includes gas dispersion and describes what happens when a gas is released. Ten leak scenarios are examined including a release into a vehicle parked in a garage. The chapter describes how gases with different densities might behave differently in this partially confined space.

Chapter 16 gives an overview of the requirements for shipping compressed gas and cryogenic fluids under current DOT regulations, as well as the basic requirements for safe storage, use, and handling of compressed gases and cryogenic fluids under OSHA regulations. It also describes when these DOT and OSHA regulations apply.

Table 16.8(a) depicts the minimum distance from hydrogen systems to various outdoor exposures, based on current NFPA requirements. This data is grouped by quantity of hydrogen, with data for 0-3000 standard cubic feet (scf), 3000-15000 scf, and in excess of 15000 scf. (view Hydrogen and Fuel Cell Safety Report Conversion Tables). As the hydrogen community conducts significant research and validation on hydrogen risks and appropriate separation distances, it is possible that this table, along with provisions in the model codes may be revised in the future.

As I read the book, two things struck me. Firstly, this book has the answers for so many of the questions people have asked me over the years with many references for further investigation. Secondly, if this book had been around during my Freshman year of Welding Engineering at the Ohio State University, I'm certain it would have been mandatory reading. If you want to learn more about safe handling and use of compressed gases, this book is for you.

You may purchase a copy of the NFPA Guide here.

Thank you to the NFPA for providing a copy of the Guide for review.